(a) Show that for a gas obeying the van der Waals equation of state (10.3.9), [C_{P}-C_{V}=N kleft{1-frac{2...
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(a) Show that for a gas obeying the van der Waals equation of state (10.3.9),
\[C_{P}-C_{V}=N k\left\{1-\frac{2 a}{k T v^{3}}(v-b)^{2}\right\}^{-1}\]
(b) Also show that, for a van der Waals gas with constant specific heat \(C_{V}\), an adiabatic process conforms to the equation
\[(v-b) T^{C_{V} / N k}=\text { const.; }\]
compare with equation (1.4.30).
(c) Further show that the temperature change resulting from an expansion of the gas (into vacuum) from volume \(V_{1}\) to volume \(V_{2}\) is given by
\[T_{2}-T_{1}=\frac{N^{2} a}{C_{V}}\left(\frac{1}{V_{2}}-\frac{1}{V_{1}}\right)\]
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