A PVT system has a line of continuous phase transitions (a lambda line) separating two phases, I
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A PVT system has a line of continuous phase transitions (a lambda line) separating two phases, I and II, of the system. The molar heat capacity cp and the thermal expansivity ap are different in the two phases. Compute the slope (dP/dT)coex of the A line in terms of the temperature T, the molar volume v, Acp = cp - cp, and Aap = ap - ap.
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