Treatment of a 3 acylindole with LiAlH 4 in (CH3CH2)2O reduces the carbonyl all the way to a CH 2 group Explain by a plausible mechanism CR Excess LIAIH, (CH,CH,),0, A CH,R OH LIAIH, (Compare CR C R) H H...

Treatment of a 3-acylindole with LiAlH 4 in (CH3CH2)2O reduces the carbonyl all the way to a

Question:

Treatment of a 3-acylindole with LiAlH₄ in (CH3CH2)2O reduces the carbonyl all the way to a CH₂ group. Explain by a plausible mechanism.

CR Excess LIAIH, (CH,CH,),0, A CH,R OH LIAIH, (Compare CR -C-R) H H

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For book-img-for-question

Organic Chemistry structure and function

ISBN: 978-1429204941

6th edition

Authors: K. Peter C. Vollhardt, Neil E. Schore

See More Books

Question Posted: May 12, 2020 06:01 AM

See More Questions

The commercial synthesis of a useful heterocyclic derivative requires treatment of a mixture of aldopentoses (derived from corncobs, straw, etc.) with hot acid under dehydrating conditions. The...
Carboxylic acids having a second carbonyl group two atoms away lose CO2 (decarboxylate.) through an intermediate enolate ion when treated with base. Write the mechanism of this decarboxylation...
Proteins can be cleaved specifically at the amide bond on the carboxyl side of methionine residues by reaction with cyanogen bromide, BrC = N. The reaction occurs in several steps: (a) The first step...
M/s Active Builders Ltd. invested in the shares of another company (with an intention to hold the shares for short term period )on 31st October, 2016 at a cost of Rs.4,50,000. It also earlier...
(i) In the model with one endogenous explanatory variable, one exogenous explanatory variable, and one extra exogenous variable, take the reduced form for y2, (15.26), and plug it into the structural...
Identify and discuss the ways discharge may be brought about by operation of law.
Describe how the SDLC pertains to the development of this application. Describe the tasks that need to be accomplished in each phase. Indicate who should perform the tasks: MRV, an outsource...
The bank portion of the bank reconciliation for Katsaris Company at August 31, 2014, was as follows: The adjusted cash balance per bank agreed with the cash balance per books at August 31. The...
Express the confidence interval 29.7%3.1% in the form of a trilinear inequality. %
Taussig Technologies Corporation (TTC) has been growing at a rate of 20% per year in recent years. This same supernormal growth rate is expected to last for another 2 years (g1 = g2 = 20%). a. If D0...
Heterocycle C, C 5 H 6 O, exhibits 1 H NMR spectrum C and is converted by H 2 and Raney nickel into compound D, C 5 H 10 O, with spectrum D. Identify compounds C and D. (Note: The coupling constants...
The sequence in the margin is a rapid synthesis of one of the heterocycles in this chapter. Draw the structure of the product, which has 1 H NMR spectrum F. 'H NMR 1 H 1 H 3 H 1H. 9.2 8.5 8.4 7.9 7.8...
If the coefficient of static friction at A is ? s = 0.4 and the collar at B is smooth so it only exerts a horizontal force on the pipe, determine the minimum distance x so that the bracket can...
Check that [edgm $][$ cdgm $]$ is a graphical model. Education Gender MS Dep CIRS
Use the information provided in P3-9B. Required a. Prepare closing entries at December 31 in general journal form using the Income Summary account. b. After the closing entries are posted, calculate...
If the light bulb in Figure $33.8 a$ is $1.0 \mathrm{~m}$ in front of the mirror, how far behind the mirror is the image? Data from Figure 33.8a (a) Rays shows path of light that travels from...
$300.0 \mathrm{kmol} / \mathrm{h}$ of a saturated liquid feed that is $40.0 \mathrm{~mol} \% \mathrm{n}$-nonane (C9) and $60.0 \mathrm{~mol} \% \mathrm{n}$-decane (C10) at $11.0 \mathrm{kPa}$...
Show that for a Hamiltonian of the form \[H=-G \sum_{m, m^{\prime}>0} a_{m^{\prime}}^{\dagger} a_{-m^{\prime}}^{\dagger} a_{-m} a_{m}\] the energy eigenvalues for the quasispin model of Problem 31.1...
Add a method bubbleSort to the class ArraySorter, as given in Listing 7.10, that performs a bubble sort of an array. The bubble sort algorithm examines all adjacent pairs of elements in the array...
A new car sold for $31,000. If the vehicle loses 15% of its value each year, how much will it be worth after 10 years?
The following 1H NMR spectrum is that of an alcohol, C8H10O. Propose a structure. TMS 6. Chemical shift (8) 3 O ppm 10 8. Intensity
Propose structures for alcohols that have the following 1H NMR spectra: (a) C5H12O (b) C8H10O Part (a) TMS O ppm 10 3 2 Chemical shift (8) Part (b) TMS O ppm 10 8. 6. 4 3 2 Chemical shift (8) Inten
Propose structures for alcohols that have the following 1H NMR spectra: (a) C9H12O (b)C8H10O2 Part (a) TMS 10 O ppm Chemical shift (8) Part (b) TMS O ppm 10 8. Chemical shift (8) Intensity Intensity...
Content Area The following accounts appear in the ledger of Monroe Entertainment Co. All accounts have normal balances. Accounts Payable $471 Fees Earned $2,347 Accounts Receivable 741 Insurance...
Concord Importers provides the following pension plan information. Fair value of pension plan assets, January 1, 2020 $2,192,000 Fair value of pension plan assets, December 31, 2020 2,549,000...
CELL PHONE USAGE NOT ALLOHC Company's accounts receivable for 2024: 7. The following information relates to Acme Compa

Treatment of a 3-acylindole with LiAlH 4 in (CH3CH2)2O reduces the carbonyl all the way to a

Question:

CR Excess LIAIH, (CH,CH,),0, A CH,R OH LIAIH, (Compare CR -C-R) H H

Step by Step Answer:

O 11 CR OLI ...View the full answer

Organic Chemistry structure and function

Students also viewed these Sciences questions