The brilliant white glow of fireworks is due to the combustion of magnesium in air at a

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The brilliant white glow of fireworks is due to the combustion of magnesium in air at a high temperature. But is that combustion spontaneous, in the thermodynamic sense, at ordinary temperatures? You can find out by calculating the total entropy change. Assess whether the combustion of magnesium, 2 Mg(s) + O(g) → 2 MgO(s), is spontaneous at 25°C under standard conditions, given AS = 217 J.K- and AH = -1202 kJ.

ANTICIPATE You can safely anticipate that all combustion reactions are spontaneous at normal temperatures.
PLAN Find the entropy change in the surroundings by using Eq. 2, then calculate the total entropy change by using Eq. 1.total entropy entropy change change of system Stot AS = + entropy change of surrondings AS Surr (1)AS surr  at constant temperature and pressure T (2)

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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