Th e chemical industry converts hydrocarbons of low molecular mass to larger and more useful compounds. Calculate

Question:

Th e chemical industry converts hydrocarbons of low molecular mass to larger and more useful compounds. Calculate the change in enthalpy for the synthesis of cyclohexane (C6H12), a compound used in the production of nylon, from ethylene.3C,H4(g)  C%H12(0)  = ? =

Use the information in Example 5.8 and the thermochemical equation for the combustion of cyclohexane:C6H12(e) +902(g)  6CO(g) + 6HO(0)  = -3920 kJ

Strategy

Arrange the thermochemical equations so that the reactant, C2H4, is on the left and the product, C6H12, is on the right. The other products and reactants should all cancel so that the desired reaction is all that remains.

Example 5.8

Hydrogenation of hydrocarbons is an important reaction in the chemical industry. A simple example is the hydrogenation of ethylene to form ethane. Calculate the enthalpy change for CH4(g) + H(g)  CH6(g) ethylene ethane AH = ?

Use the following thermochemical equations to determine the overall enthalpy change.H(g) +-10(g)   HO(l) CH4(g) + 30(g)  2CO(g) + 2HO(0) CH6(g) +0(g)  2CO(g) + 3HO(!) AH = -285.8 kJ AH = -1411

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Related Book For  book-img-for-question

Chemistry Principles And Practice

ISBN: 9780534420123

3rd Edition

Authors: Daniel L. Reger, Scott R. Goode, David W. Ball

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