Consider the following reaction in which [P 3 O 10 ] 5 (see Fig. 15.21) displaces the

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Consider the following reaction in which [P₃O₁₀]⁵⁻ (see Fig. 15.21) displaces the carbonate ion to give a mixture of linkage isomers:

(a) Suggest possible coordination modes for the [P₃O₁₀]⁵⁻ion in the products, given that an octahedral metal centre is retained.

(b) How might the products formed in the reaction be influenced by the pH of the solution?

Figure 15.21.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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Consider the following reaction in which [P 3 O 10 ] 5 (see Fig. 15.21) displaces the

Question:

H₂N H₂N NH3 Co NH3 c=0 + Nas[P3010], H₂O/H+

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To answer your questions regarding the coordination modes of the P3O105 ion in an octahedral complex and the influence of pH on the reaction products ...View the full answer

Inorganic Chemistry

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