D. N. Kursanov, a Russian chemist, proved that the bond that is broken in the hydroxideion- promoted
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D. N. Kursanov, a Russian chemist, proved that the bond that is broken in the hydroxideion- promoted hydrolysis of an ester is the acyl C-O bond, rather than the alkyl C-O bond, by studying the reaction of the following ester with HO-/H2O:
a. Which of the products contained the 18O label?
b. What product would have contained the 18O label if the alkyl C-O bond had broken?
Transcribed Image Text:
alkyl C-o bond CH,CH, C 18 o-CH,CH3 acyl C-O bond
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a As the acyl CO bond is broken in the hydroxide ionpr...View the full answer
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