Draw a curved-arrow mechanism for the Amadori rearrangement in Eq. 27.50. Let H 3 O + and

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Draw a curved-arrow mechanism for the Amadori rearrangement in Eq. 27.50. Let H₃O⁺ and H₂O be the acid–base pair, present as necessary. HO HO HOCH Amadori rearrangement -CH=N-Hb glucose-Hb imine (Schiff base) HO OH HO HCH, -CHOH 11

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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Question Posted: Dec 08, 2023 08:56 AM

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Draw a curved-arrow mechanism for the Amadori rearrangement in Eq. 27.50. Let H 3 O + and

Question:

HO HO HOCH₂ ОН Amadori rearrangement -CH=N-Hb ОН glucose-Hb imine (Schiff base) HO НО Н OH HO НО HỌCH, -CH₂OH Н 11 ОН -CH,-NH-НЬ internal rotation -CH2-ЙН_НЬ НО ОН ОН -ОН CH,-NH-НЬ Amadori product (27.50)

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Reference the mechanism in Eqs 2424ab and ...View the full answer

Organic Chemistry

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