The reaction of butylamine, with 1-bromobutane in 60% aqueous ethanol follows the rate law rate 5 k[butylamine][1-bromobutane]

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The reaction of butylamine, CH3(CH)3 NH2,with 1-bromobutane in 60% aqueous ethanol follows the rate law rate 5 k[butylamine][1-bromobutane]

The product of the reaction is(CH,CH,CH,CH,),NH, Br .

The following very similar reaction, however, has a first-order rate law:NH -Br A + NH Br rate = k[A]

Give a mechanism for each reaction that is consistent with its rate law and with the other facts about nucleophilic substitution reactions. Use the curved-arrow notation.

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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