Indicator error. Consider the titration in Figure 10-2 in which the equivalence-point pH in Table 10-2 is
Question:
Indicator error. Consider the titration in Figure 10-2 in which the equivalence-point pH in Table 10-2 is 9.25 at a volume of 10.00 mL.
(a) Suppose you used the yellow-to-blue transition of thymol blue indicator to find the end point. According to Table 10-3, the last trace of green disappears near pH 9.6. What volume of base is required to reach pH 9.6? The difference between this volume and 10 mL is the indicator error.
(b) If you used cresol red, with a color change at pH 8.8, what would be the indicator error?
Figure 10-2
Table 10-2
Buffer Excess region OH- 12 11 Maximum 10 Equivalence point slope (inflection point) Minimum slope (inflection point) 6. pH = pK, Ve/2 4 4 6 8. 10 12 14 16 V, (mL) 2. 7,
Step by Step Answer:
a The volume of base required to reach pH 96 can be calculated using the HendersonHasselbalch equati...View the full answer
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A substance that alters color in solution over a constrained range of pH values is known as a pH indicator or acid-base indicator. The indicator chemical just needs to alter color slightly in order to be noticed. Indicators work on the basis that they react with water to produce the hydrogen cation H+ or hydronium ion H3O+. The indicator molecule\\\'s color changes as a result of the reaction. Since indicators have distinct color ranges for color change, they can occasionally be combined to provide color changes over a wider pH range.
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