NiO adopts the cubic NaCl-type structure while PtO adopts the cooperite structure shown below. (a) What factor

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NiO adopts the cubic NaCl-type structure while PtO adopts the cooperite structure shown below.

(a) What factor do you think is responsible for the differing crystal chemistry preferences of these two compounds? Consider the splitting and occupation of the d orbitals for each compound.

(b) Which structure type do you think PdO will adopt? Would it be possible to tell from a magnetic measurement?

Ni NiO (rock salt) PtO (cooperite) O Pt

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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Question Posted: Jan 23, 2024 10:03 AM

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NiO adopts the cubic NaCl-type structure while PtO adopts the cooperite structure shown below. (a) What factor

Question:

Ni NiO (rock salt) PtO (cooperite) O Pt

Step by Step Answer:

Figure 525 Figure 72 a Pt is larger than Ni so it is not possible to attribute the lower coordinatio...View the full answer

Solid State Materials Chemistry

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