Question: The rotational constants B 0 have been determined for three isotopic derivatives of chloroacetylene: Assume that the carbon isotope is 12 C in all cases.

The rotational constants B₀ have been determined for three isotopic derivatives of chloroacetylene:

Assume that the carbon isotope is ¹²C in all cases. Calculate the three bond distances in chloroacetylene. What approximations or assumptions do you have to make to work this problem with the information given?

H-C=C-37C1, 5572.3 MHz; D-C=C-7C1, 5084.2 MHz; and H-C=C-5C1, 5684.2 MHz.

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