Account for each of the transformations shown in Fig. P15.84 with a curved-arrow mechanism. (Dont try to

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Account for each of the transformations shown in Fig. P15.84 with a curved-arrow mechanism. (Don’t try to explain any percentages.) In part (d), identify X; give the mechanisms for both the formation and the subsequent reaction of X; and explain why the equilibrium for the reaction of X strongly favors the products.(a) (b) CHCH=CHCH-OH conc. HBr CH3 H3C COH CH3 HO+ heat HSO4 -15 C CHCH=CHCH-Br + CH3CHCH=CH + H0 T (84%) Br

CH3  "A r - Scho H H + heat O CH3 H (d) HC CH(CH3)2 a-phellandrene Figure P15.84 i HC. HC || + EtOC-C=C-COET

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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