In the unimolecular isomerization of cyclobutane to butylene, the following values for kuni as a function of

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In the unimolecular isomerization of cyclobutane to butylene, the following values for kuni as a function of pressure were measured:

390 210 110 Po (Torr) 760 11.1 10.8 10.3 9.58 kuni (s-)

Assuming that the Lindemann mechanism accurately describes this reaction, determine k1 and the ratio k€“1/k2

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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