All Matches
Solution Library
Expert Answer
Textbooks
Search Textbook questions, tutors and Books
Oops, something went wrong!
Change your search query and then try again
Toggle navigation
FREE Trial
S
Books
FREE
Tutors
Study Help
Expert Questions
Accounting
General Management
Mathematics
Finance
Organizational Behaviour
Law
Physics
Operating System
Management Leadership
Sociology
Programming
Marketing
Database
Computer Network
Economics
Textbooks Solutions
Accounting
Managerial Accounting
Management Leadership
Cost Accounting
Statistics
Business Law
Corporate Finance
Finance
Economics
Auditing
Ask a Question
Search
Search
Sign In
Register
study help
sciences
chemistry principles and practice
Questions and Answers of
Chemistry Principles And Practice
Consider the nitrogen–oxygen bond lengths in In which ion is the bond predicted to be longest? In which is it predicted to be the shortest? Explain briefly. NOŽ,
The compound disulfur dinitride, S2N2, has a cyclic structure with alternating sulfur and nitrogen atoms. Draw two Lewis structures for S2N2, one that places an octet about each atom and another that
Use the octet rule to predict the element (E) from the second period that would be the central atom in the following ions. (a) EF (b) EF+
Use Table 9.4 to calculate an approximate enthalpy change for(a) The reaction of H2 and C2H2 to form 1 mol C2H6.(b) The reaction of molecular hydrogen and molecular nitrogen to form 1 mol
Use Table 9.4 to calculate an approximate enthalpy change for(a) The combustion of 1 mol C2H4 in excess molecular oxygen to form gaseous water and CO2.(b) The reaction of 1 mol formaldehyde, H2CO,
The equation for the combustion of gaseous methanol isUsing the bond dissociation enthalpies, estimate the enthalpy change for this reaction. 2CH3OH(g) + 30₂2(g) →2CO₂(g) + 4H₂O(g)
Using Table 9.4, calculate an approximate enthalpy change for(a) The reaction of molecular hydrogen (H2) and molecular oxygen (O2) in the gas phase to produce 2 mol water vapor.(b) The reaction of
Using Table 9.4, calculate the energy required to break all of the bonds in one mole of the following compounds.(a) CH2CF2(b) N2H4Table 9.4 TABLE 9.4 Bond Energies (kJ/mol)* Single
Which molecule has the most polar bond: N2, BrF, or ClF? Use an arrow to show the direction of polarity in each bond.
Using Table 9.4, calculate the energy required to break all of the bonds in one mole of the following compounds.(a) NH3(b) CH3OHTable 9.4 TABLE 9.4 Bond Energies (kJ/mol)* Single
Write the Lewis structures of HNNH and H2NNH2. Predict which molecule has the greater N–N bond energy.
Write the Lewis structures of H2CNH and H3CNH2. Predict which molecule has the greater C–N bond energy.
For the following species, write a resonance structure with an octet about the central atom and a second resonance structure that minimizes formal charges. (a) [o [] 0-s-o 2- (b) [&] O-CI-O
For the following species, write a resonance structure with an octet about the central atom and a second resonance structure that minimizes formal charges. (a) [O-CI-O]- (b) [0_1_0_1]]
For the following species, write a resonance structure with an octet about the central atom and a second resonance structure that minimizes formal charges. (a) O H-O-D-0 O (b) O H-O-P-0-H O H
For the following species, write a resonance structure with an octet about the central atom and a second resonance structure that minimizes formal charges. (a) O-Se-0 (b) O 0-8-0
Write the Lewis structures for the following species, and indicate whether each is an odd-electron species, an electron-deficient species, or an expanded valence shell species.(a) BI3(b) IF5(c) HN2
Write the Lewis structures for the following species, and indicate whether each is an odd-electron species, an electron-deficient species, or an expanded valence shell species. Th ere is only one
Write the Lewis structures for the following species, and indicate whether each is an odd-electron species, an electron-deficient species, or an expanded valence shell species. (a) IF3 (b) ICla (c)
Write the Lewis structures of the following molecules, and indicate whether each is an odd-electron molecule, an electron-deficient molecule, or an expanded valence shell
Write all possible resonance structures for the species with the skeleton structures shown below. In each case, which resonance structure is the most important? (a) H-O-N O (b) O-N
Draw all resonance structures for methylisocyanate, CH3NCO, a toxic gas used in the manufacturing of pesticides. Which resonance structures are the most important?
Write all resonance structures of chlorobenzene, C6H5Cl, a molecule with the same cyclic structure as benzene. In all structures, keep the C–Cl bond as a single bond. Which resonance structures are
Write all resonance structures of toluene, C6H5CH3, a molecule with the same cyclic structure as benzene. Which resonance structures are the most important?
Write all possible resonance structures for the species with the skeleton structures shown below. In each case, which resonance structure is the most important? (a) H-C (b) H-O-N-O
Write all possible resonance structures for the species with the skeleton structures shown below. In each case, which resonance structure is the most important? (a) [N-N-N] (b) [- 0-C 2-
Write all possible resonance structures for the species with the skeleton structures shown below. In each case, which resonance structure is the most important? (a) Η Ο H-C-C-Ν Η (b) Ο [ ] _0-N-0
Write all possible resonance structures for the species with the skeleton structures shown below. In each case, which resonance structure is the most important? (a) H H C-N-N (b) [O-C-N]-
Show all possible resonance structures for each of the following molecules or ions:(a) Nitrate ion,(b) Nitrous oxide (laughing gas), N2O (where the bonding is in the order N - N - O) NO3
Write all possible resonance structures for the following species. Assign a formal charge to each atom. In each case, which resonance structure is the most important?(a) (nitrogen is
Predict which connectivity, SCN- or CSN-, is the more favorable arrangement.
The connectivity of HNO could be either HNO or HON. Draw a Lewis structure for each and predict which connectivity is the more favorable arrangement.
The connectivity of H3CN could be H2CNH or HCNH2 as well. Draw a Lewis structure for each of these two structures and predict which connectivity is the more favorable arrangement.
The Understanding section in Example 9.10 showed two possible arrangements for the atoms in H2CO. We concluded that structure A, repeated here, was better. A third possible structure follows as
Write the Lewis structures showing formal charge for the following species. (a) CIO (b) NCCN (c) SOCI₂
Write the Lewis structures showing formal charge for the following species. (a) FSO3 (b) HNC (c) SO₂Cl₂
Write the Lewis structures showing formal charge for the following species. (a) CN- (b) HCO₂
Write the Lewis structures showing formal charge for the following species.(a) NO2 (b) OCS(c) SO3
Given the bonds C - N, C - H, C - Br, and S - O,(a) Which atom in each is the more electronegative?(b) Which of these bonds is the most polar?
For each pair of bonds, indicate which has the greater polarity, and show the direction of the dipole moment.(a) N-O, C-O(b) Si-Ge, Ge-C(c) S-H, O-H(d) B-C, B-Si
Arrange the members of each of the following sets of elements in order of increasing electronegativities.(a) Pb, C, Sn, Ge(b) S, Na, Mg, Cl(c) P, N, Sb, Bi(d) Se, Ba, F, Si, Sc
Arrange the members of each of the following sets of elements in order of increasing electronegativity (use only a periodic table to determine your answer).(a) Cl, I, Br(b) Br, Ca, Ga(c) O, K, Ge
Which atom in each of the following pairs has the greater electronegativity? Use only a periodic table to determine your answer.(a) O, S(b) K, Ge(c) Br, Te
Which atom in each of the following pairs has the greater electronegativity? Use only a periodic table to determine your answer.(a) Br, I(b) S, Cl(c) C, N
Write the Lewis structure for each species, with the skeleton structure shown below. (a) (c) F F F F-B-F F c-c F F (b) (d) H H H H Η Ο C-C-C-H H 1 C-C-C-C-H
Write the Lewis structure for each compound, with the skeleton structure shown below. (a) H-C-C-H (c) H H H C-C-C-N (b) H-O-CI (d) H-0-0-H
Write the Lewis structure for each compound, with the skeleton structure shown below. (a) F-0-0-F (b) (c) Η Η C-C Cl Cl (d) Ο H-C-0-H Η Η Η H-C-N-C-H Η Η
Write the Lewis structure for each compound, with the skeleton structure shown below. (a) (c) Η Ο Ο H-C-C-Η Η Η Η T H=C=C=C Η (b) Η H Η H (d) Η N-0-H N-N H
Draw a Lewis structure for each of the following molecules or ions.(a) CS2(b) BF4 (c) HNO2 (where the bonding is in the order HONO)(d) OSCl2 (where S is the central atom)
Write the Lewis structure for the following species.(a) CCl4(b) NO(c) BCl-4
What is the bond order between each pair of bonded atoms of the compounds in Exercise 9.36?Exercise 9.36Draw Lewis structures for the following species. (The skeleton is indicated by the way the
Write Lewis structures for these molecules or ions.(a) CN(b) Tetrafluoroethylene, C2F4, the molecule from which Teflon is made(c) Acrylonitrile, CH2CHCN, the molecule from which Orlon is made
Write the Lewis structure for the following compounds.(a) AsH3(b) ClF(c) CF3OH
What is the bond order between each pair of bonded atoms of the compounds in Exercise 9.35?Exercise 9.35Write the Lewis structure for each of the following compounds. Label electrons as bonding pairs
Write the Lewis structure for each of the following compounds. Label electrons as bonding pairs or lone pairs.(a) H2S(b) H2CO(c) PF3Formaldehyde, H2CO, is a toxic gas that was found to be at
Write the formula of the simplest neutral compound made from the following:(a) Silicon and hydrogen(b) Phosphorus and chlorine(c) Sulfur and fluorine
Write the formula of the simplest neutral compound made from the following:(a) Carbon and fluorine(b) Nitrogen and iodine(c) Oxygen and chlorine
Arrange the following series of compounds in order of increasing lattice energies.(a) LiCl, NaCl, BeCl2(b) MgO, MgF2, MgBr2(c) MgCl2, BeO, BeCl2
Draw Lewis structures for the following species. (The skeleton is indicated by the way the molecule is written.)(a) Cl2CO(b) H3C–CN
Arrange the following series of compounds in order of increasing lattice energies.(a) NaBr, NaCl, KBr(b) MgO, CaO, CaCl2(c) LiF, BeF2, BeO
Of the ionic solids CaO and BaO, which has the greater lattice energy? Explain your choice.
What is a radical, and why do radicals violate the octet rule?
What elements are most likely to form electron-deficient molecules?
Discuss factors that relate formal charges in Lewis structures to the relative stabilities of different connectivities of atoms in molecules and relative stabilities of different resonance structures.
Draw the Lewis structure of BeF2.
Write all of the resonance structures for NCO-, where the carbon atom is the central atom. Indicate the relative contribution of each.
Give the characteristics of a correct Lewis structure.
Use formal charge to predict which of the following skeleton structures is more likely to be correct for a molecule with the formula H2CO. H H C-O A H-C-O-H B
Describe the main difference between covalent and ionic bonding.
Draw the Lewis structure of the NH−2 anion showing all non-zero formal charges.
Write the electron configuration of Co3+.
Of the ionic solids LiCl and LiI, which has the greater lattice energy? Explain your choice.
Write the formulas of the ionic compounds that will form from the two pairs of elements given. Of each pair, which has the greater lattice energy? Explain your choice.(a) Potassium and sulfur;
Write the formulas of the ionic compounds that will form from the two pairs of elements given. Of each pair, which has the greater lattice energy? Explain your choice.(a) Lithium and oxygen; sodium
Write the Lewis symbol for the following species.(a) A potassium atom(b) A nitrogen atom(c) A boron atom(d) F-
Write the Lewis symbol for the following species.(a) A lithium atom(b) S2-(c) A magnesium atom(d) A bromine atom
Write the Lewis symbol for the following species.(a) A sulfur atom(b) I-(c) A beryllium atom(d) Ga2+
Explain why the bond dissociation energy for HCl is measured exactly, but that for a C–C bond is an average.
Define bond dissociation energy. Describe a method that uses bond dissociation energies to calculate approximate enthalpies of chemical reactions.
Which elements can form expanded valence shell molecules? Do the two xenon compounds shown below have an expanded valence shell? Explain your answer. XeF2 XeF4
Use Table 9.4 to calculate an approximate enthalpy of reaction forTable 9.4StrategyUse Equation 9.2, being careful to substitute the correct number of moles of bonds being formed or broken. Also,
Describe what is meant by resonance structures.
Calculate the enthalpy of reaction for the reaction of N2 and H2 to form 2 mol NH3, using data from Table 9.4.Table 9.4 TABLE 9.4 Bond Energies (kJ/mol)* Single
Draw the important resonance structures for chloric acid, HClO3.
Explain how formal charges are assigned to atoms in Lewis structures.
Write the important resonance structures for H2SO3. Experimental evidence supports the importance of Lewis structures that contain atoms with expanded valence shells rather that those containing high
Write the Lewis structure for XeF4.StrategyWrite the Lewis structure for this molecule in the normal way, but place any excess electrons available after each element satisfies the octet rule on the
Compare the trends in electronegativity and ionization energy within(a) A group and(b) A period. Explain any differences.
Write the Lewis structure for SF6.
Draw the Lewis structure of AlH3.StrategyDraw the Lewis structure in the normal way but realize that, in certain cases, it is not possible to place eight electrons around the central atom.
Outline the trends in the electronegativities of the representative elements. Which element has the highest electronegativity?
Write the resonance structures for thiocyanate anion, SCN-, and indicate the relative contribution of each.
What is a polar bond, and under what circumstances does it occur?
Write the resonance structures of benzene, C6H6. Th e skeleton structure of this molecule is a six-member ring of carbon atoms, with one hydrogen atom bonded to each carbon atom.StrategyWrite all
Explain the different behaviors expected from HCl and Cl2 when each is placed between two oppositely charged plates.
Write all the resonance structures for NO-2, an ion with O–N–O connectivity.
There are two possible ways to connect the atoms in hydrogen cyanide: HCN and HNC. Write the Lewis structures and use formal charges to predict which is the more likely structural
Draw the Lewis structure of ozone, O3, showing formal charges if needed.StrategyThe strategy is the same as for Example 9.8.Example 9.8Draw the Lewis structure of the ammonium cation, showing formal
Assign formal charges to the atoms in N2O, given the Lewis structure: N=N=0
Define the octet rule and rationalize why the rule applies to most compounds made up of representative elements.
Showing 1600 - 1700
of 2907
First
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Last